162790-77-4Relevant academic research and scientific papers
Evaluation of 2-bromocyclohexenone acetals as vehicles for the introduction of C-7 oxygen preliminary to the synthesis of taxane diterpenes
Paquette,Su,Bailey,Montgomery
, p. 897 - 902 (1995)
The coupling of an optically pure, camphor-derived, β,γ-unsaturated, bicyclic ketone with a suitable vinyl organometallic is recognized to result in 1,2-addition from the endo face. Anionic oxy-Cope rearrangement of these carbinols proceeds via an 'endo-c
