16284-76-7Relevant academic research and scientific papers
Naeherungsverfahren zur Ermittlung von Teilgeschwindigkeitskonstanten eines komplexen, linear abhaengigen Reaktionsmodells
Fuellbier, Barbara,Haberland, Detlef
, p. 52 - 56 (2007/10/02)
A system of linear dependent competitive secondary reactions is regard to, for the kinetical investigation of the synthesis of dimethoate.An analytical solution of this simultane differential equation system is not possible.Various most integral methods of approximation for the solution of this problem are proposed and their usefulness are tested on the basis of experimental data.A complete solution of the differential equations, which is permitted to test the quality of the applied methods of approximations, are obtained by French-transformation.A good correspondence between experimental and calculated data is obtained by using a numerical procedure of Runge-Kutta.
Kinetic Investigations on the Aminolysis Reaction of the Dithiophosphoric Esters with Monomethylamine in Binary Methanol/Water - Mixtures
Fuellbier, B.,Klemmer, K.,Wettengel, A.,Haberland, D.
, p. 911 - 918 (2007/10/02)
The influence of the solvent polarity on the aminolysis reaction between O,O-dimethyl-S-(methoxycarbonylmethyl)-dithiophosphoricacidester (1) and monomethylamine, which is the main reaction of the "Dimethoate" synthesis, is investigated.The observed effects are compared with those of the alkylation of these esters by monomethylamine.Both reactions show a similar dependence on the solvent polarity.
