1630-02-0Relevant academic research and scientific papers
Reactions of 1-methoxycarbonyl-3-cyclohexene and 3,4-epoxy-1-methoxycarbonyl-cyclohexane with tert-butoxy radical
Zaitseva,Narizhnaya
, p. 480 - 485 (2007/10/03)
Reactions of 1-methoxycarbonyl-3-cyclohexene and 3,4-epoxy-1-methoxycarbonylcyclohexane (as a 63:37 mixture of trans and cis isomers or pure trans isomers) with tert-butoxy radical at 413 K yield oligomeric products. In the case of epoxy derivatives, 1-methoxycarbonyl-4-cyclohexen-3-ol, 1-methoxycarbonyl-4-cyclohexen-3-one, and 1-methoxycarbonyl-3-cyclohexanone are also formed. This set of products indicates that tert-butoxy radical abstracts a hydrogen atom from the 2-position of the cyclohexene ring and from the 2,3- or 4,5-positions of the cyclohexane ring. 1996 MAEe Cyrillic signΚ Hayκa/Interperiodica Publishing.
