138124-73-9

Upstream product

• 186581-53-3 diazomethane 
• 67-56-1 methanol 
• 76704-24-0 c-3,4-epoxy-r-1-cyclohexanecarboxylic acid 
• 1630-02-0 methyl (1RS,3RS,4SR)-3,4-epoxycyclohexanecarboxylate 

Downstream Products

• 138230-39-4 (1R,2R,4S)-4-Hydroxymethyl-2-methoxy-cyclohexanol 
• 138008-22-7 (1S,3R,4R)-4-Hydroxy-3-methoxy-cyclohexanecarboxylic acid 

Relevant academic research and scientific papers

Baeyer-Villiger oxidation of norbornan-7-ones: Long-range substituent effects on regioselectivity

The regioselectivity of the Baeyer-Villiger oxidation of norbornan-7-ones can be steered by the distal 2-endo-substituents present. Hydrolysis of the resulting bicyclic lactones provides a stereospecific route to functionalized cyclohexanes.

Regiochemical Control of the Ring-Opening of 1,2-Epoxides by Means of Chelating Processes. 2. Synthesis and Reactions of the cis- and trans-Oxides of 4-cyclohexene, 3-Cyclohexenemethanol, and Methyl 3-Cyclohexenecarboxylate

The synthesis of the diastereoisomeric epoxides cis-1b-d and trans-2b-d and the products of their ring-opening by various nucleophiles are described.The results of the ring-openings of the trans-epoxides 2b-d can be rationalized by combining stereoelectro