163189-52-4Relevant academic research and scientific papers
A Reaction of γ-Chalcogen-substituted Prop-2-ynyl Cations with Mild Nucleophiles
Yoshimatsu, Mitsuhiro,Shimizu, Hiroshi,Kataoka, Tadashi
, p. 149 - 150 (1995)
γ-Chalcogen-substituted prop-2-ynyl cations are generated by the reactions of diethyl acetals 1 and 2 with BF3-Et2O and react with various mild nucleophiles without isomerisation to allenyl cations to afford the prop-2-ynylated products 3a-e and 5a-c in good yields.
