163215-98-3

Upstream product

• 18951-85-4 (R)-citronellic acid 
• 163215-96-1 (R)-3,7-Dimethyl-oct-6-enoic acid (R)-3-methyl-cyclohex-2-enyl ester 
• 18890-22-7 (R)-3-methylcyclohex-2-en-1-ol 

Downstream Products

• 248915-99-3 (2R,3R)-3,7-dimethyl-2((1S)-1-methyl-2-cyclohexenyl)-6-octen-1-ol tosylate 
• 163215-99-4 (2R,3R)-3,7-dimethyl-2((1S)-1-methyl-2-cyclohexenyl)-6-octene 
• 163216-00-0 (6R,7R)-2,6,7-trimethyl-7-((1S)-1-methyl-2-cyclohexenyl)-heptan-2-ol 
• 248916-00-9 (S)-3-Methyl-3-((1R,2R)-1,2,6-trimethyl-6-triethylsilanyloxy-heptyl)-cyclohexanol 
• 163216-01-1 Triethyl-[(5R,6R)-1,1,5-trimethyl-6-((S)-1-methyl-cyclohex-2-enyl)-heptyloxy]-silane 
• 163216-02-2 (3S)-3-methyl-3-((1R,2R)-6-triethylsilyloxy-1,2,6-trimethylheptyl)cyclohexanone 
• 181116-74-5 C₄₃H₈₆O₃Si₃ 
• 181116-72-3 (1S,5R)-1,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methylene-3-[2-[(S)-3-methyl-3-((1R,2R)-1,2,6-trimethyl-6-triethylsilanyloxy-heptyl)-cyclohex-(E)-ylidene]-eth-(Z)-ylidene]-cyclohexane 

Relevant academic research and scientific papers

Total Synthesis of (+)-Aplykurodinone-1

Starting from (R)-citronellic acid and (R)-seudenol, the total synthesis of (+)-aplykurodinone-1, a highly degraded marine steroid, has been achieved in 11 steps and in 19% overall yield with excellent stereochemical control. In addition to the features s

Synthesis, biological activity, and conformational analysis of four seco-D-15,19-bisnor-1α,25-dihydroxyvitamin D analogues, diastereomeric at C17 and C20

The synthesis of four CD-ring-modified 19-nor-1α,25-dihydroxyvitamin D3 derivatives lacking C15, referred to as 6C analogues, and diastereomeric at C17 and C20 is described. The synthesis involves an Ireland-Claisen rearrangement of a 3-methyl-