163236-97-3Relevant academic research and scientific papers
Palladium(ii)-catalyzed stereoselective synthesis of: C-glycosides from glycals with diaryliodonium salts
Das, Mrinmoy,Lee, Jiande,Liu, Xue-Wei,Pal, Kumar Bhaskar
, p. 2242 - 2251 (2020)
An efficient palladium(ii) mediated C-glycosylation of glycals with diaryliodonium salts is described, providing a new strategy for the synthesis of 2,3-dideoxy C-Aryl glycosides with excellent stereoselectivity. The C-glycosylation of a diverse range of
Remarkable oxidation stability of glycals: Excellent substrates for cerium(IV)-mediated radical reactions
Linker, Torsten,Schanzenbach, Dirk,Elamparuthi, Elangovan,Sommermann, Thomas,Fudickar, Werner,Gyollai, Viktor,Somsak, Laszlo,Demuth, Wolfgang,Schmittel, Michael
supporting information; experimental part, p. 16003 - 16010 (2009/05/15)
The remarkable stability of glycals under oxidative conditions becomes apparent by their redox data in solution, computed HOMO energies, and behavior on the addition of electrophilic radicals generated in the presence of cerium(IV) ammonium nitrate. Oxida
Convenient syntheses and transformations of 2-C-malonyl carbohydrates
Yin, Jian,Sommermann, Thomas,Linker, Torsten
, p. 10152 - 10167 (2008/09/18)
2-C-malonyl carbohydrates were synthesized in only few steps and high yields by radical additions of malonates to glycals. For the first time, the undesired formation of nitrates was completely suppressed with anhydrous cerium ammonium nitrate (CAN) as ox
Oxidation of Fully Protected Glycals by Hypervalent Iodine Reagents
Kirschning, Andreas
, p. 1228 - 1232 (2007/10/02)
A new application of organoiodine(III) is presented.Fully protected glycals are directly converted into 2,3-dihydro-4H-pyran-4-ones by benzene (PhI(OH)OTs, 1).The detailed study reveals that this conversion is independent of the rel
