163273-23-2Relevant academic research and scientific papers
Bis(fluorosulfuryl)imide: A Broensted acid catalyst for the addition of allyltrimethylsilane to carbonyl compounds
Kaur, Gurmeet,Manju, Kavita,Trehan, Sanjay
, p. 581 - 582 (1996)
The Broensted acid HN(SO2F)2 catalyses the addition of allyltrimethylsilane to carbonyl compounds to give the corresponding homoallylic alcohols in high yields.
Mesoporous aluminosilicate-catalyzed allylation of carbonyl compounds and acetals
Ito, Suguru,Hayashi, Akira,Komai, Hirotomo,Yamaguchi, Hitoshi,Kubota, Yoshihiro,Asami, Masatoshi
experimental part, p. 2081 - 2089 (2011/04/19)
A mesoporous aluminosilicate (Al-MCM-41) was found to be an effective heterogeneous catalyst for the reaction of both carbonyl compounds and acetals with allylsilanes to afford the corresponding homoallyl silyl ethers and homoallyl alkyl ethers, respectively. Both the mesoporous structure and the presence of aluminum moiety were indispensable for the high catalytic activity of Al-MCM-41. Moreover, Al-MCM-41 could catalyze the reaction of acetals chemoselectively in the presence of the corresponding carbonyl compounds. The solid acid catalyst Al-MCM-41 could be recovered easily by filtration and could be reused three times without a significant loss of catalytic activity.
Mesoporous aluminosilicate-catalyzed allylation of aldehydes with allylsilanes
Ito, Suguru,Yamaguchi, Hitoshi,Kubota, Yoshihiro,Asami, Masatoshi
scheme or table, p. 2967 - 2969 (2009/08/07)
Mesoporous aluminosilicate (Al-MCM-41) was found to catalyze the allylation of both aromatic and aliphatic aldehydes with allylsilanes although amorphous silica-alumina or mesoporous silicates (MCM-41, SBA-15) could not catalyze the reaction under the sam
Cr-waste free catalytic carbonyl addition reactions with polymer-immobilized CrF2
Kurosu, Michio
, p. 3395 - 3399 (2007/10/03)
A monomeric [Cr(pyridine)4F2]+Br- is immobilized onto the dipyridyl-TentaGel resin. Allylations of aldehydes with 5-10 mol % of the CrF2-dipyridyl-TentaGel resin 2/Mn/TMSCl in THF provide the correspo
Indium Triiodide (InI3)-Catalyzed Allylation of Carbonyl Compounds by Allylic Tins
Miyai, Takashi,Inoue, Katsuyuki,Yasuda, Makoto,Baba, Akio
, p. 699 - 700 (2007/10/03)
Indium triiodide is an effective catalyst for the allylation of aldehydes via the transmetallation with allylic tin compounds. Moreover, the chelation-controlled allylation of α-alkoxyketones proceeded with a catalytic amount of indium triiodide.
