16336-55-3

Basic information

• Product Name: Phenanthrene, 9-(phenylthio)-
• CAS NO: 16336-55-3
• Molecular Formula: C20H14S
• Molecular Weight: 286.397
• Mol File: 16336-55-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Phenanthrene, 9-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenanthrene, 9-(phenylthio)-(16336-55-3)
• EPA Substance Registry System: Phenanthrene, 9-(phenylthio)-(16336-55-3)

Safety Data

• Hazardous Substances Data: 16336-55-3(Hazardous Substances Data)

Upstream product

• 573-17-1 9-bromophenanthrene 
• 108-98-5 thiophenol 
• 17024-12-3 9-iodo-phenanthrene 
• 947-72-8 9-chlorophenanthrene 
• 930-69-8 sodium thiophenolate 
• 122776-46-9 9-Benzenesulfinyl-phenanthrene 

Relevant articles and documents

Synthesis of 9-alkyl- and 9-arylthiophenanthrenes

A simple method for the preparation of 9-alkyl- and 9-arylthiophenanthrenes from 9-bromophenanthrene and a thiol is described.

A semiconducting supramolecular Co(ii)-metallohydrogel: an efficient catalyst for single-pot aryl-S bond formation at room temperature

A novel mechanically stable supramolecular Co(ii)-metallohydrogel has been synthesized. Cobalt(ii) nitrate hexahydrate and monoethanolamine, as a low molecular weight organic gelator, are used to get the gel. The mechanical stability of the supramolecular hydrogel was analyzed. The morphology of the supramolecular metallohydrogel was scrutinized. The semiconducting features of the metallohydrogel were studied. The conducting properties of the Co(ii)-metallohydrogel establish a Schottky barrier diode type nature. The catalytic nature of the Co(ii)-metallohydrogel based room temperature single pot aryl-S coupling reaction was explored. Most interestingly, the Co(ii)-metallohydrogel based catalytic aryl-S coupling reaction does not require any column-chromatographic purification protocol to get pure aryl-thioethers. Thus, through this work a semiconducting Schottky barrier diode application and catalytic role in the room temperature single pot aryl-S coupling reaction of a supramolecular Co(ii)-metallohydrogel have been explored.

Cobalt-catalyzed aryl-sulfur bond formation

A new cobalt-catalyzed coupling of aryl halides with thiophenols and alkanethiols is reported. A variety of aryl sulfides can be prepared in excellent yields under mild reaction conditions using 1-2 mol % of Col2(dppe) and Zn. This new cobalt-catalyzed coupling represents an interesting addition to previously known methods to synthesize thioethers.