16343-57-0

Upstream product

• 3818-97-1 2,3-homoptropone 
• 116460-78-7 1,6-Bis-(2-chloro-phenyl)-1,6-diphenyl-hexa-2,4-diyne-1,6-diol; compound with bicyclo[5.1.0]octa-3,5-dien-2-one 
• 16343-57-0 1α,2α,4α,6α-Tricyclo<4.2.0.0^2,4>oct-7-en-5-on 
• 86436-19-3 (-)-1,6-diphenyl-1,6-di(o-chlorophenyl)-hexa-2,4-diyne-1,6-diol 

Downstream Products

• 16343-57-0 1α,2α,4α,6α-Tricyclo[4.2.0.0^2,4]oct-7-en-5-on 
• 19093-14-2 1α,2α,4α,6α-Tricyclo<4.2.0.0^2,4>octan-5-on 

Relevant academic research and scientific papers

ENANTIOCONTROLL OF PHOTOREACTIONS IN THE SOLID STATE

Irradiation of crystalline complexes of prochiral guest compounds and optically active host compounds in the solid state gave optically active photoreaction products.For example, irradiation of the complexes of tropolone alkyl ether, nitrones, and oxoamid

CONTROL OF PHOTOREACTIONS OF EIGHT MEMBERED RING DI- AND TRIENONES IN A CRYSTALLINE INCLUSION COMPLEX WITH OPTICALLY ACTIVE 1,6-DI(o-CHLOROPHENYL)-1,6-DIPHENYLHEXA-2,4-DIYNE-1,6-DIOL

By complexing with the title host compound, flipping equilibrium of cycloocta-2,4,6-trien-1-one was frozen in one optical conformer as a 2:1 complex, which upon irradiation gave optically active bicycloocta-4,7-dien-2-one.Irradiation of a 1:2 complex of cycloocta-2,4-dien-1-one and the same host compound gave an optically active dimer, anti-tricyclo2,9>hexa-deca-7,11-diene-3,16-dione.