163456-89-1

Basic information

• Product Name: N-benzyl-(6R,1'S,2'R,3'R,4'R)-6-(3'-O-benzyl-1',2':5',6'-di-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)-2,3-didehydropiperidine-4-one
• Synonyms: N-benzyl-(6R,1'S,2'R,3'R,4'R)-6-(3'-O-benzyl-1',2':5',6'-di-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)-2,3-didehydropiperidine-4-one
• CAS NO: 163456-89-1
• Molecular Weight: 507.627
• Mol File: 163456-89-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl-(6R,1'S,2'R,3'R,4'R)-6-(3'-O-benzyl-1',2':5',6'-di-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)-2,3-didehydropiperidine-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-(6R,1'S,2'R,3'R,4'R)-6-(3'-O-benzyl-1',2':5',6'-di-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)-2,3-didehydropiperidine-4-one(163456-89-1)
• EPA Substance Registry System: N-benzyl-(6R,1'S,2'R,3'R,4'R)-6-(3'-O-benzyl-1',2':5',6'-di-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)-2,3-didehydropiperidine-4-one(163456-89-1)

Safety Data

• Hazardous Substances Data: 163456-89-1(Hazardous Substances Data)

Upstream product

• 4258-02-0 2,3:5,6-di-O-isopropylidene-D-glucose diethyl dithioacetal 
• 100-39-0 benzyl bromide 
• 149557-49-3 4-O-benzyl-2,3:5,6-di-O-isopropylidene-D-glucose diethyl dithioacetal 
• 163456-88-0 4-O-benzyl-2,3:5,6-di-O-isopropylidene-aldehydo-D-glucose 

Downstream Products

• 163456-91-5 N-benzyl-(2R,4S,1'S,2'R,3'R,4'R)-4-hydroxy-2-(3'-O-benzyl-1',2'-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)piperidine 
• 163456-92-6 (S)-[(4R,5S)-5-((2R,4S)-1-Benzyl-4-hydroxy-piperidin-2-yl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-benzyloxy-acetaldehyde 
• 163456-93-7 (2S,3R,4S)-4-((2R,4S)-1-Benzyl-4-hydroxy-piperidin-2-yl)-2-benzyloxy-3,4-dihydroxy-butyraldehyde 
• 163456-90-4 N-benzyl-(2R,4S,1'S,2'R,3'R,4'R)-4-hydroxy-2-(3'-O-benzyl-1',2':5',6'-di-O-isopropylidene-1',2',3',4',5'-pentahydroxy-1'-pentyl)piperidine 

Relevant articles and documents

Cycloaddition Reactions of Carbohydrate Derivatives. Part VI. Quinolizidine Analogs of Castanospermine

Octahydroquinolizine-1,2,3,8-tetraols 12, 16 and 23, analogs of castanospermine, were synthesized from D-glucose, L-arabinose and D-mannose, respectively, using hetero-Diels-Alder reactions of sugar-derived azomethines as the key step.