163514-11-2

Basic information

• Product Name: 4-isopropyl-2-(pent-4-ynyl)cyclohexanone
• Synonyms: 4-isopropyl-2-(pent-4-ynyl)cyclohexanone
• CAS NO: 163514-11-2
• Molecular Weight: 206.328
• Mol File: 163514-11-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-isopropyl-2-(pent-4-ynyl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-isopropyl-2-(pent-4-ynyl)cyclohexanone(163514-11-2)
• EPA Substance Registry System: 4-isopropyl-2-(pent-4-ynyl)cyclohexanone(163514-11-2)

Safety Data

• Hazardous Substances Data: 163514-11-2(Hazardous Substances Data)

Upstream product

• 2468-55-5 5-iodopent-1-yne 
• 19620-35-0 8-(propan-2-ylidene)-1,4-dioxaspiro[4.5]decane 
• 5432-85-9 4-isopropyl-cyclohexanone 
• 4746-97-8 cyclohexanedione monoethylene ketal 
• 866606-96-4 (5S)-5-isopropyl-2-oxo-1-(pent-4-ynyl)cyclohexanecarboxylic acid methyl ester 

Relevant articles and documents

Highly diastereoselective formation of spirocyclic compounds via 1,5-hydrogen transfer: A total synthesis of (-)-erythrodiene

(Chemical Equation Presented) A highly stereoselective synthesis of (-)-erythrodiene starting from 4-isopropylcyclohexanone is described. The key reactions are an asymmetric methoxycarbonylation of the starting ketone and a highly diastereoselective radical cascade involving addition of a phenylthiyl radical to a terminal alkyne followed by a 1,5-hydrogen transfer and a 5-exo-cyclization.