16358-40-0Relevant academic research and scientific papers
Copper-Catalyzed, N-Directed Csp3-H Trifluoromethylthiolation (-SCF3) and Trifluoromethylselenation (-SeCF3)
Modak, Atanu,Pinter, Emily N.,Cook, Silas P.
supporting information, p. 18405 - 18410 (2019/11/19)
A direct and versatile copper-catalyzed trifluoromethylthiolation and trifluoromethylselenation of primary, secondary, and tertiary aliphatic C-H bonds was developed. The reaction provides direct access to molecules containing these emerging moieties in the presence of a wide range of common functional groups and in complex molecular environments.
Oxidative deamination of various primary amines to the corresponding carbonyl compounds by using N-tert-butylphenylsulfinimidoyl chloride
Matsuo, Jun-Ichi,Kawana, Asahi,Fukuda, Yoshio,Mukaiyama, Teruaki
, p. 712 - 713 (2007/10/03)
Various linear and non-linear primary amines were oxidatively deaminated to afford the corresponding carbonyl compounds in good to excellent yields by the following procedure: (i) initial formation of their N-cyclohexylated or N-mesylated derivatives, (ii) subsequent oxidation of these derivatives by using N-tert-butylphenylsulfinimidoyl chloride (1) and DBU, (iii) one-pot acid-hydrolysis of thus formed imines to carbonyl compounds.
Reductive deprotection of allyl, benzyl and sulfonyl substituted alcohols, amines and amides using a naphthalene-catalysed lithiation
Alonso, Emma,Ramon, Diego J.,Yus, Miguel
, p. 14355 - 14368 (2007/10/03)
The reaction of different protected alcohols, amines and amides with lithium and a catalytic amount of naphthalene (4 mol %) in THF at low temperature leads to their deprotection under very mild reaction conditions, the process being in many cases chemoselective.
