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163630-07-7

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163630-07-7 Usage

General Description

2,6-Bis(tributylstannyl)pyridine is a chemical compound that consists of a pyridine ring with tributylstannyl groups attached to the 2 and 6 positions. The tributylstannyl groups are organotin compounds that contain four butyl groups attached to a tin atom. This chemical is commonly used in organic synthesis as a reagent for cross-coupling reactions, where it facilitates the formation of carbon-carbon bonds. It is a versatile reagent that is particularly useful in the synthesis of complex organic molecules and pharmaceuticals. However, it is important to handle this compound with caution as organotin compounds can be toxic and harmful to the environment.

Check Digit Verification of cas no

The CAS Registry Mumber 163630-07-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,3,6,3 and 0 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 163630-07:
(8*1)+(7*6)+(6*3)+(5*6)+(4*3)+(3*0)+(2*0)+(1*7)=117
117 % 10 = 7
So 163630-07-7 is a valid CAS Registry Number.

163630-07-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name tributyl-(6-tributylstannylpyridin-2-yl)stannane

1.2 Other means of identification

Product number -
Other names Pyridine,2,6-bis(tributylstannyl)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:163630-07-7 SDS

163630-07-7Downstream Products

163630-07-7Relevant articles and documents

Synthesis, structure, and properties of oligo-tridentate ligands; covalently assembled precursors of coordination arrays

Hanan, Garry S.,Schubert, Ulrich S.,Volkmer, Dirk,Riviere, Emmanuel,Lehn, Jean-Marie,Kyritsakas, Nathalie,Fischer, Jean

, p. 169 - 182 (2007/10/03)

Oligo-tridentate ligands based on alternating pyridines and pyrimidines were synthesised by Stille-type carbon-carbon bond-forming reactions. The terpyridine-like sites are designed to coalign upon metal complexation, giving rise to organized and rigidly spaced metal ions. Peripheral functionalization of the basic bis-tridentate framework was explored. The heterocycles in the ligands are in an all-trans conformation about the interannular bonds as indicated by comparison of their 1H NMR spectra. An X-ray crystal structure analysis of the nonchiral tris-tridentate ligand 2a reveals a helical structure in the solid state. The seven heterocycles form a helical structure with resulting overlap of the terminal pyridines. Their centroid-to-centroid distance is 4.523 A with 38.8° between the planes. NMR investigations support a helical conformation in solution as well. Electrochemical and UV absorption measurements indicate that the LUMO resides on the pyrimidine moiety of the ligands.

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