1637487-08-1

Basic information

• Product Name: C₂₃H₃₈N₂O
• CAS NO: 1637487-08-1
• Molecular Weight: 358.568
• Mol File: 1637487-08-1.mol

Chemical Properties

• CAS DataBase Reference: C₂₃H₃₈N₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₃H₃₈N₂O(1637487-08-1)
• EPA Substance Registry System: C₂₃H₃₈N₂O(1637487-08-1)

Safety Data

• Hazardous Substances Data: 1637487-08-1(Hazardous Substances Data)

Upstream product

• 1637487-31-0 C₁₉H₃₂Cl₃NO₃ 
• 17642-49-8 rac-hexadecen-3-ol 
• 62-53-3 aniline 
• 1637487-34-3 C₁₇H₃₃NO₂ 

Relevant articles and documents

[3,3]-sigmatropic rearrangements of fluorinated allyl (thio)cyanates - A to ol for the synthesis of fluorinated (thio)ureas

The first (thio)cyanate to iso(thio)cyanate rearrangements based on 2-fluoroallylic alcohols are presented. Long-chain 2-fluoroallylic alcohols were converted to corresponding N-unsubstituted carbamates by treatment with trichloroacetyl isocyanate. Dehydration using trifluoroacetic anhydride in the presence of triethylamine formed intermediate allylic cyanates, which immediately underwent sigmatropic rearrangement to fluorinated allyl isocyanates. Without isolation the latter delivered fluorinated ureas by addition of amines. The thiocyanate to isothiocyanate rearrangements started from the same fluorinated allylic alcohols, which were first converted to mesylates. Heating in THF with potassium thiocyanate led to fluorinated allyl isothiocyanates, via [3,3]-sigmatropic rearrangement of intermediate allyl thiocyanates. The formed products were further reacted with amines to fluorinated thioureas. Schweizerische Chemische Gesellschaft.