1637769-06-2Relevant academic research and scientific papers
Hydrothermal synthesis and crystal structure of a complex with pyrogallic acid and N-donor ligand: 2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline
Huang, Yan-Ju,Yan, Yong-Sheng,Du, Gang,Liang, Yue
, p. 1483 - 1486 (2014)
The complex [Ni(MOPIP)3(C6H5O 3)]n·nH2O 1 (C6H 5O3 = pyrogallic acid, MOPIP = 2-(4-methoxyphenyl)-1H- imidazo[4,5-f][1,10] phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG, and single-crystal X-ray diffraction. Complex 1 crystallizes in the monoclinic system, space group P 21/c, with α = 17.249 (3), b = 15.014 (3), c = 21.437 (4) A, β = 92.14 (3), V = 5547.7 (19) A3, and Z = 4 [at 293 (2) K]. In the crystal structure, the nickel atom is six coordinated with six nitrogen atoms from MOPIP ligand, showing a slightly distorted octahedral geometry. Furthermore, it exhibits a zero-dimensional (0D) structure with Ni-MOPIP as building units. The complex 1 extends 3D supramolecular structure through the hydrogen bonds and the π-π stacking interactions enhance the stability of the complex. Copyright
