163811-52-7

Basic information

• Product Name: 1-methoxy-3-(triisopropylsilyloxy)-1,3-butadiene
• Synonyms: 1-methoxy-3-(triisopropylsilyloxy)-1,3-butadiene
• CAS NO: 163811-52-7
• Molecular Weight: 256.461
• Mol File: 163811-52-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-methoxy-3-(triisopropylsilyloxy)-1,3-butadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-3-(triisopropylsilyloxy)-1,3-butadiene(163811-52-7)
• EPA Substance Registry System: 1-methoxy-3-(triisopropylsilyloxy)-1,3-butadiene(163811-52-7)

Safety Data

• Hazardous Substances Data: 163811-52-7(Hazardous Substances Data)

Upstream product

• 51731-17-0 trans-4-methoxy-3-buten-2-one 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 602302-21-6 (3R,5aS,9aS,10aS)-6-methoxy-5a-(methoxycarbonyl)-5-oxo-3-phenyl-8-(triisopropylsilyloxy)-2,3,9,9a,10,10a-hexahydro-6H-oxazolo[3,2-b]isoquinoline 

Relevant articles and documents

Asymmetric hetero-diels-alder reaction of danishefsky's dienes with α-carbonyl esters catalyzed by an indium(III)-PyBox complex

An efficient catalytic enantioselective hetero-Diels-Alder reaction of Danishefsky's dienes with α-carbonyl esters using a chiral In(III)-pybox complex has been demonstrated. This protocol offers several advantages, including mild reaction conditions, relatively low catalyst loading, and good to excellent enantioselectivities. Furthermore, the absolute configurations of the new alkynyl-containing products were determined by CD spectra in combination with TD-DFT calculations.