16387-85-2Relevant academic research and scientific papers
Accelerated SuFEx Click Chemistry For Modular Synthesis**
Barrow, Andrew S.,Gialelis, Timothy L.,Homer, Joshua A.,Koelln, Rebecca A.,Moses, John E.,Smedley, Christopher J.
supporting information, (2021/12/10)
SuFEx click chemistry is a powerful method designed for the selective, rapid, and modular synthesis of functional molecules. Classical SuFEx reactions form stable S?O linkages upon exchange of S?F bonds with aryl silyl-ether substrates, and while near-per
Synthesis and insecticidal activity of sulfonate derivatives of sesamol against Mythimna separata in vivo
Che, Zhi-Ping,Yang, Jin-Ming,Shan, Xi-Jie,Tian, Yue-E,Liu, Sheng-Ming,Lin, Xiao-Min,Jiang, Jia,Hu, Mei,Chen, Gen-Qiang
, p. 678 - 688 (2019/06/13)
A series of sulfonate derivatives of sesamol were synthesized and evaluated for their insecticidal activity against a crop-threatening agricultural pest, the pre-third-instar larvae of Mythimna separata in vivo. Among all the target compounds, compounds 3
Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis
Chow, Wing Kin,So, Chau Ming,Lau, Chak Po,Kwong, Fuk Yee
supporting information; experimental part, p. 6913 - 6917 (2011/08/03)
Top of the one-pots! The first palladium-catalyzed borylation of aryl tosylates and mesylates is described. The reaction conditions are mild and provide excellent functional-group compatibility (e.g., R=CN, CHO, COOMe, C(O)R, NH2, or NH-indole; see scheme). Pd/MeO-CM-phos allows one-pot sequential reactions in the preparation of unsymmetrical biaryls. Copyright
Palladium-catalyzed carbonylation of aryl tosylates and mesylates
Munday, Rachel H.,Martinelli, Joseph R.,Buchwald, Stephen L.
, p. 2754 - 2755 (2008/09/19)
A general protocol for the palladium-catalyzed carbonylation of aryl tosylates and mesylates to form esters has been developed using a catalyst system derived from Pd(OAc)2 and the bulky, bidentate dcpp ligand. The system operates under mild conditions: atmospheric CO pressure and temperatures of 80-110 °C. A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic tosylates and mesylates, and the reaction shows wide functional group tolerance. Copyright
