1638755-48-2Relevant academic research and scientific papers
1,2-N-migration in a gold-catalysed synthesis of functionalised indenes by the 1,1-carboalkoxylation of ynamides
Adcock, Holly V.,Langer, Thomas,Davies, Paul W.
, p. 7262 - 7266 (2014/06/23)
Unique α-hemiaminal ether gold carbene intermediates were accessed by a gold-catalysed 1,1-carboalkoxylation strategy and evolved through a highly selective 1,2-N-migration. This skeletal rearrangement gave functionalised indenes, and isotopic labelling c
