163977-20-6Relevant articles and documents
Intrinsic Reactivities of Some Carbanions in ?-Adduct Forming Reactions
Crampton, Michael R.,Stevens, Andrew J.
, p. 1715 - 1720 (2007/10/02)
Kinetic and equilibrium data are reported for nucleophilic attack in methanol at unsubstituted ringpositions of 1,3,5-trinitrobenzene, 2,4,6-trinitrotoluene and 1-chloro-2,4,6-trinitrobenzene by carbanions derived from dimethyl malonate, ethyl cyanoacetate and 4-nitro-, 4-cyano- and 2-cyanobenzyl cyanides.The results are used to determine intrinsic reactivities for the carbanions in these ?-adduct forming reactions and are discussed in terms of the electronic and solvent reorganisation occurring during reaction.
