163977-86-4Relevant academic research and scientific papers
Reactions of episulfonium ions from the sulfenylation of alkenes and from phenylthio migration: Kinetic vs thermodynamic control
Bird, Paul,Eames, Jason,Fallis, Alex G.,Jones, Ray V. H.,Roddis, Marc,Sturino, Claudio F.,O'Sullivan, Susan,Warren, Stuart,Westwell, Martin S.,Worrall, Julia
, p. 1909 - 1912 (1995)
The formation of the same cyclic ethers from the sulfenylation of unsaturated alcohols and from acid catalysed phenylthio migration on diols via the same intermediate can be explained by kinetic and thermodynamic control. Both reactions are synthetically useful. A result from a previous Tetrahedron Letter is corrected.
