Reactions of episulfonium ions from the sulfenylation of alkenes and from phenylthio migration: Kinetic vs thermodynamic control

DOI: 10.1016/0040-4039(95)00110-X

Source and publish data:

Tetrahedron Letters p. 1909 - 1912 (1995)

Update date:2022-07-30

Topics:

Authors:

Bird, Paul

Eames, Jason

Fallis, Alex G.

Jones, Ray V. H.

Roddis, Marc

Sturino, Claudio F.

O'Sullivan, Susan

Warren, Stuart

Westwell, Martin S.

Worrall, Julia

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Article abstract of DOI:10.1016/0040-4039(95)00110-X

The formation of the same cyclic ethers from the sulfenylation of unsaturated alcohols and from acid catalysed phenylthio migration on diols via the same intermediate can be explained by kinetic and thermodynamic control. Both reactions are synthetically useful. A result from a previous Tetrahedron Letter is corrected.

Full text of DOI:10.1016/0040-4039(95)00110-X

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