Reactions of episulfonium ions from the sulfenylation of alkenes and from phenylthio migration: Kinetic vs thermodynamic control

DOI: 10.1016/0040-4039(95)00110-X

Source and publish data:

Tetrahedron Letters p. 1909 - 1912 (1995)

Update date:2022-07-30

Topics:

Authors:

Bird, Paul

Eames, Jason

Fallis, Alex G.

Jones, Ray V. H.

Roddis, Marc

Sturino, Claudio F.

O'Sullivan, Susan

Warren, Stuart

Westwell, Martin S.

Worrall, Julia

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00110-X

The formation of the same cyclic ethers from the sulfenylation of unsaturated alcohols and from acid catalysed phenylthio migration on diols via the same intermediate can be explained by kinetic and thermodynamic control. Both reactions are synthetically useful. A result from a previous Tetrahedron Letter is corrected.

Full text of DOI:10.1016/0040-4039(95)00110-X

Products guided by the article

Product name:5-Methyl-5-phenylsulfanyl-hexane-1,4-diol

Cas No:163977-86-4

R&D Labs maybe for 163977-86-4

WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.

Contact:13861062998

Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Xi'an HO-SHINE Bio-Technology Co., Ltd

Contact:+86 (29) 8248-5435/18292020086

Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China

Relevant to this article

Promoting Effect of Crystal Water Leading to Catalyst-Free Synthesis of Heteroaryl Thioether from Heteroaryl Chloride, Sodium Thiosulfate Pentahydrate, and Alcohol

Doi:10.1021/acs.joc.9b01670
(2019)
Identification of 3,5-Dihydro-2-aryl-1H-pyrazolo<3,4-c>quinoline-1,4(2H)-diones as Novel High-Affinity Glycine Site N-Methyl-D-aspartate Antagonists

Doi:10.1021/jm00012a024
(1995)
Activator-Promoted Aryl Halide-Dependent Chemoselective Buchwald-Hartwig and Suzuki-Miyaura Type Cross-Coupling Reactions

Doi:10.1021/acs.orglett.0c01600
(2020)
SYNTHESIS OF 1,3-DIHYDRO-5(R)-7,8-ETHYLENEDIOXY-2H-1,4-BENZO-DIAZEPIN-2-ONES

Doi:10.1007/BF01169826
(1994)
New pyrazolyl-nicotinic acids, methyl esters, and 1,3,4-oxadiazolyl- pyrazolyl-pyridine tricyclic scaffold derivatives from 6-hydrazinylnicotinic acid hydrazide hydrate

Doi:10.1002/jhet.2110
(2014)
Amination of dinitrobenzenes with liquid methylamine/potassium permanganate

Doi:10.1002/recl.19951140104
(1995)

Article Doi