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2-Methoxy-5-(tributylstannyl)pyridine is an organometallic compound characterized by a pyridine ring with a methoxy group at the 2nd position and a tributylstannyl group at the 5th position. The tributylstannyl group features four butyl groups attached to a central tin atom, providing unique reactivity and stability to the molecule. 2-Methoxy-5-(tributylstannyl)pyridine is recognized for its high stability, selectivity, and utility in various chemical reactions, particularly in palladium-catalyzed cross-coupling processes.

164014-93-1

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164014-93-1 Usage

Uses

Used in Organic Synthesis:
2-Methoxy-5-(tributylstannyl)pyridine is utilized as a nucleophilic organostannane reagent in organic synthesis, facilitating the replacement of the tributylstannyl group with other functional groups in organic molecules. This property is crucial for the formation of new chemical bonds and the synthesis of complex organic compounds.
Used in Pharmaceutical Production:
In the pharmaceutical industry, 2-Methoxy-5-(tributylstannyl)pyridine is employed as a key intermediate in the synthesis of various drugs. Its reactivity and stability contribute to the production of pharmaceuticals with specific therapeutic properties.
Used in Agrochemical Synthesis:
Similarly, in agrochemical synthesis, 2-Methoxy-5-(tributylstannyl)pyridine serves as an essential component in the creation of pesticides and other agrochemicals, leveraging its organometallic properties to form active ingredients with targeted biological activity.
Caution in Laboratory Settings:
Due to the potential toxicity associated with organotin compounds, 2-Methoxy-5-(tributylstannyl)pyridine requires careful handling and usage in laboratory environments. Proper safety measures should be implemented to minimize exposure and ensure the well-being of researchers and the integrity of the experimental conditions.

Check Digit Verification of cas no

The CAS Registry Mumber 164014-93-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,4,0,1 and 4 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 164014-93:
(8*1)+(7*6)+(6*4)+(5*0)+(4*1)+(3*4)+(2*9)+(1*3)=111
111 % 10 = 1
So 164014-93-1 is a valid CAS Registry Number.
InChI:InChI=1/C6H6NO.3C4H9.Sn/c1-8-6-4-2-3-5-7-6;3*1-3-4-2;/h2,4-5H,1H3;3*1,3-4H2,2H3;/rC18H33NOSn/c1-5-8-13-21(14-9-6-2,15-10-7-3)17-11-12-18(20-4)19-16-17/h11-12,16H,5-10,13-15H2,1-4H3

164014-93-1 Well-known Company Product Price

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  • Aldrich

  • (SYX00029)  6-Methoxy-3-(tributylstannyl)pyridine  AldrichCPR

  • 164014-93-1

  • SYX00029-1G

  • 1,930.50CNY

  • Detail

164014-93-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methoxy-5-(tributylstannyl)pyridine

1.2 Other means of identification

Product number -
Other names 6-Methoxy-3-(tributylstannyl)pyridine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:164014-93-1 SDS

164014-93-1Relevant academic research and scientific papers

Efficient one-pot cross-coupling of two aryl halides by stannylation/stille reaction in water under microwave irradiation

Tan, Xin,Zhou, Zi Jie,Zhang, Jia Xin,Duan, Xin Hong

supporting information, p. 5153 - 5157 (2014/09/29)

A simple and highly efficient one-pot approach has been developed for the Pd(PPh3)4-catalyzed cross-coupling of two different aryl or heteroaryl bromides/iodides. This method involves the combined use of microwave irradiation and water as a single solvent to achieve sequential stannylation and Stille cross-coupling reactions, which allows rapid access to a wide variety of biaryls in good to high yields. Furthermore, utilizing this step-economical protocol, 2,5-dibromopyridine was iteratively diarylated and the Boscalid intermediate was also synthesized in a one-pot manner. Copyright

2-Aminopyridine compounds and use thereof as drugs

-

, (2008/06/13)

The present invention provides 2-aminopyridine compound having an excellent adenosine receptor (A1, A2a, A2b receptors) antagonism, which is represented by the following formula: (wherein, R1 represents cyano gr

2-AMINOPYRIDINE COMPOUNDS AND USE THEREOF AS DRUGS

-

, (2008/06/13)

The present invention provides 2-aminopyridine compound having an excellent adenosine receptor (A1, A2a, A2b receptors) antagonism, which is represented by the following formula: (wherein, R1 represents cyano gr

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