164022-87-1Relevant academic research and scientific papers
Chemo- and regioselective reductive transposition of allylic alcohol derivatives via iridium or rhodium catalysis
Lundgren, Rylan J.,Thomas, Bryce N.
, p. 958 - 961 (2016)
We report highly chemo- and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity to that of established Pd-catalysis. These Rh- and Ir-catalysed transformations proceed under mild conditions and enable selective deoxygenation in the presence of functional groups that are susceptible to reduction by metal hydrides.
