Chemical Communications p. 958 - 961 (2016)
Update date:2022-08-05
Topics:
Lundgren, Rylan J.
Thomas, Bryce N.
We report highly chemo- and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity to that of established Pd-catalysis. These Rh- and Ir-catalysed transformations proceed under mild conditions and enable selective deoxygenation in the presence of functional groups that are susceptible to reduction by metal hydrides.
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