16407-55-9

Usage

Uses

Used in Organic Synthesis:
N-ALLYLBENZOTHIAZOLIUM BROMIDE is used as an intermediate for organic synthesis, enabling the creation of various chemical compounds and materials.
Used in Antimicrobial Applications:
N-ALLYLBENZOTHIAZOLIUM BROMIDE is used as an antimicrobial agent, providing protection against harmful microorganisms and promoting cleanliness and hygiene in various settings.

Upstream product

• 95-16-9 1,3-Benzothiazole 
• 106-95-6 allyl bromide 

Downstream Products

• 1415666-30-6 C₁₉H₁₉NOS 
• 1415666-24-8 C₁₇H₁₃Cl₂NOS 
• 1415666-25-9 C₁₇H₁₄BrNOS 
• 1415666-28-2 C₁₇H₁₅NO₂S 
• 1415666-20-4 C₁₇H₁₅NOS 

Relevant academic research and scientific papers

Intercepting the Breslow intermediate via Claisen rearrangement: Synthesis of complex tertiary alcohols without organometallic reagents

A novel Claisen rearrangement in which the Breslow intermediate is engaged as a hydroxy-substituted N,S-ketene acetal to provide complex 3° alcohols without the use of organometallic reagents is reported. The reaction constitutes an unprecedented reactivi

One-step entry to olefin-tethered N,S-heterocyclic carbene complexes of ruthenium with mixed ligands

A series of Ru(ii) mixed-ligand complexes RuBr2(PPh 3)2(N-AyBzTh) (Ay = prop-2-enyl; BzTh = benzothiazol-2-ylidene) (4), RuBr(OAc)(PPh3)(N-MeAyBzTh) (5), RuBr(OAc)(PPh3)(N-MeBnBzTh)2 (MeBn

Pd(ii) complexes of N,S-heterocyclic carbenes with pendant and coordinated allyl function and their Suzuki coupling activities

3-(2-Propenyl)benzothiazolium bromide (A) provides a direct and simple entry to Pd(ii) complexes with N,S-heterocyclic carbene (NSHC) ligands functionalized with an allyl pendant with hemilabile potential. Addition of salt A to Pd(OAc)2 eliminates HOAc and affords the bis(carbene) complexes cis-[PdBr2(NHSC)2] (cis-1, NSHC = 3-(2-propenyl) benzothiazolin-2-ylidene) and trans-[PdBr2(NHSC)2] (trans-1) along with the monocarbene complexes [PdBr2(NSHC)] (2) and trans-[PdBr2(benzothiazole-κN)(NSHC)] (3) as minor side products. Salt-metathesis of cis-1 with AgO2CCF3 yields the mixed dicarboxylato-bis(carbene) complex cis-[Pd(O2CCF 3)2(NSHC)2] (4). Complexes cis-1, trans-1 and 4 were characterized by multinuclear NMR spectroscopies, ESI mass spectrometry and elemental analysis. The molecular structures of complexes cis-1, 2 and 3 have been determined by X-ray single crystal diffraction. Complexes cis-1 and 4 as well as an in situ mixture of Pd(OAc)2 and salt A are active toward Suzuki-Miyaura coupling of aryl bromides and activated aryl chlorides giving good conversions. The Royal Society of Chemistry.