164145-47-5

Basic information

• Product Name: 3-Octanone, 5-hydroxy-4-methyl-2-(phenylmethoxy)-, (2S,4R,5S)-
• CAS NO: 164145-47-5
• Molecular Formula: C16H24O3
• Molecular Weight: 264.365
• Mol File: 164145-47-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Octanone, 5-hydroxy-4-methyl-2-(phenylmethoxy)-, (2S,4R,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Octanone, 5-hydroxy-4-methyl-2-(phenylmethoxy)-, (2S,4R,5S)-(164145-47-5)
• EPA Substance Registry System: 3-Octanone, 5-hydroxy-4-methyl-2-(phenylmethoxy)-, (2S,4R,5S)-(164145-47-5)

Safety Data

• Hazardous Substances Data: 164145-47-5(Hazardous Substances Data)

Upstream product

• 132489-33-9 (S)-2-benzyloxy-3-pentanone 
• 123-72-8 butyraldehyde 

Relevant articles and documents

Studies in polypropionate synthesis: High π-face selectivity in Syn and Anti aldol reactions of chiral boron enolates of lactate-derived ketones

Use of (c)Hex2Bcl/Me2NEt in the aldol reactions of the α'-benzoyloxy ketone 7 with aldehydes leads to high stereoselectivity (97-95.5% ds) for the crystalline anti adducts 11. Under similar conditions, the corresponding benzyl ether 6 favours formation of the syn adducts 9.