1643-70-5Relevant articles and documents
Direct Perfluoroalkylthiolation of Few Chalcogenols
Glenadel, Quentin,Billard, Thierry
, p. 455 - 458 (2016)
Trifluoromethanesulfenamide reagent can react with alcohols, in basic conditions, or with thiols, in catalytic acid conditions, to afford the corresponding trifluoromethanesulfenates or trifluoromethyldisulfides. The use of higher homologs of this reagent
-
Andreades,S. et al.
, p. 898 - 900 (1964)
-
A new route to thio- and selenosulfonates from disulfides and diselenides. Application to the synthesis of new thio- and selenoesters of triflic acid
Billard, Thierry,Langlois, Bernard R.,Large, Sylvie,Anker, Daniel,Roidot, Nathalie,Roure, Philippe
, p. 7545 - 7550 (2007/10/03)
Alkyl and aryl trifluoromethanethiosulfonates1 (or selenosulfonates) were prepared in one step either from alkyl and aryl sulfenyl (or selenenyl) chlorides and sodium trifluoromethanesulfinate (3) or, more generally, from disulfides (or diselenides), 3, and bromine. The second method involved trifluoromethanesulfonyl bromide as key intermediate. Benzenethiosulfonates were obtained in a similar way from disulfides, benzenesulfinate, and bromine but benzeneselenosulfonates could not be obtained by the same method from diselenides.
