164323-45-9

Upstream product

• 1117-96-0 Diazoethan 
• 2043-61-0 cyclohexanecarbaldehyde 
• 2114-41-2 (Z)-prop-1-en-1-ylcyclohexane 
• 145950-19-2 (1S,2S)-(-)-1-cyclohexylpropane-1,2-diol 
• 88196-06-9 (1S,2S)-1-phenyl-1,2-propanediol 
• 91006-75-6 (S)-2-Cyclohexyl-3-hydroxy-butyric acid 
• 2096-85-7 ethylidene triphenylarsorane 

Relevant academic research and scientific papers

Selective homologation of ketones and aldehydes with diazoalkanes promoted by organoaluminum reagents

Organoaluminum-promoted single homologation or ring expansion of ketones and aldehydes with diazoalkanes has been described, and among various organoaluminium reagents, exceptionally bulky methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is found to be highly effective for the selective homologation of various ketones and aldehydes.

A Simplified Procedure for the Stereospecific Transformation of 1,2-Diols into Epoxides

A simple, 'one-pot' procedure for the conversion of vicinal diols into epoxides via halohydrin ester intermediates has been developed.This method tolerates a wide range of functionality including acid sensitive functional groups.The transformation proceed

Process for preparing aldehydes from oxirane compounds

Aldehydes are prepared by reacting an oxirane compound with hydrogen peroxide in the presence of a boron compound.