164363-65-9Relevant academic research and scientific papers
Bidentate Ligand Transfer Reactions between Gold(I) Complexes
Bardaji, Manuel,Laguna, Antonio,Laguna, Mariano
, p. 1255 - 1258 (1995)
Reactions of the cationic derivative 2 with (1-) (X = Cl or Br) in a 1:1 or a 1:2 molar ratio afforded tri- or di-nuclear derivatives, respectively.Neutral complexes or n(μ-L-L)n> react with the cationic 2>ClO4 in 1:2 molar ratio, to give open-ring complexes ClO4.Reactions of the neutral complexes (R = Me or CH2Ph) with cationic 2 (P-P = Ph2PCH2PPh2 or Ph2PCH2CH2PPh2) led to the heterobridged dinuclear complexes ClO4.All these processes proceed via donor-acceptor intermediates, with bidentate ligand transfer.
