Bidentate Ligand Transfer Reactions between Gold(I) Complexes

DOI: 10.1039/DT9950001255

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1255 - 1258 (1995)

Update date:2022-08-03

Topics:

Authors:

Bardaji, Manuel

Laguna, Antonio

Laguna, Mariano

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Article abstract of DOI:10.1039/DT9950001255

Reactions of the cationic derivative 2 with (1-) (X = Cl or Br) in a 1:1 or a 1:2 molar ratio afforded tri- or di-nuclear derivatives, respectively.Neutral complexes or n(μ-L-L)n> react with the cationic 2>ClO4 in 1:2 molar ratio, to give open-ring complexes <(Au(PPh3))2(μ-L-L)>ClO4.Reactions of the neutral complexes (R = Me or CH2Ph) with cationic 2 (P-P = Ph2PCH2PPh2 or Ph2PCH2CH2PPh2) led to the heterobridged dinuclear complexes ClO4.All these processes proceed via donor-acceptor intermediates, with bidentate ligand transfer.

Full text of DOI:10.1039/DT9950001255

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