164400-77-5Relevant academic research and scientific papers
Metal Complexes of Biologically Important Ligands, LXXV. Synthesis of Organometallic Cobalt(III), Iridium(III) and Ruthenium(II) Complexes with α-Iminocarboxylate Ligands
Severin, Kay,Bergs, Ralph,Maurus, Michael,Mihan, Sharam,Beck, Wolfgang
, p. 265 - 274 (2007/10/02)
The α-iminocarboxylato chelate complexes RuH(CO)1)=N-R2>(PPh3)2 (1), η6-p-cymene)RuCl (3) and Cp*CoI1)=N-R2> (4) have been obtained from RuHCl(CO)(PPh3)3, 6-p-cymene)RuCl2> and Cp*Co(CO)I2, respectively and 2-oxocarboxylate/amine.The structure of (η6-p-cymene)RuCl (3a) has been determined by X-ray diffraction.By use of diamines the corresponding dinuclear cobalt and iridium complexes (5, 6) are formed from 2-oxocarboxylate and Cp*Co(CO)I2 or *IrCl2>2. - Keywords: Cobalt, Iridium, Ruthenium, 2-Iminocarboxylate, Hydride
