164530-29-4

Downstream Products

• 223260-57-9 C₄₅H₅₉BrO₈Si 

Relevant academic research and scientific papers

Chromium [II]-mediated reductive cleavage of a tertiary halide bearing three β-alkoxy groups. Synthesis of the North hexacyclic steroid unit of the cephalostatin family

Transformation of aldehyde 4 to 17nat, a hexacyclic steroid bearing the requisite functionality and spiroketal stereochemistry of the North portion of the cephalostatin family is described. The key reaction involves CrCl2 mediated reductive cle

Synthesis of the north 1 unit of the cephalostatin family from hecogenin acetate 1

Hecogenin acetate (1) was converted to North 1 azidoketone 5 involving several key transformations: (1) conversion of cyclic sulfate 33b to allylic alcohol 40 via Reich iodoso olefination; (2) E-ring annulation via intermolecular oxygen alkylation of high