Chromium [II]-mediated reductive cleavage of a tertiary halide bearing three β-alkoxy groups. Synthesis of the North hexacyclic steroid unit of the cephalostatin family

DOI: 10.1016/0040-4039(95)00307-X

Source and publish data:

Tetrahedron Letters p. 2427 - 2430 (1995)

Update date:2022-08-03

Topics:: Authors:

Fuchs

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00307-X

Transformation of aldehyde 4 to 17nat, a hexacyclic steroid bearing the requisite functionality and spiroketal stereochemistry of the North portion of the cephalostatin family is described. The key reaction involves CrCl₂ mediated reductive cle

Full text of DOI:10.1016/0040-4039(95)00307-X

Products guided by the article

Product name:C₅₀H₇₁BrO₉Si₂

Cas No:164530-29-4

R&D Labs maybe for 164530-29-4

Josun International Limited

website:http://www.josunpharma.com

Contact:+86-311-80715268 80766839

Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong

Relevant to this article

Synthesis of New α,α-Difluoro-γ-lactones through Intramolecular Radical Cyclization as a Key Reaction

Doi:10.1016/0040-4039(95)00518-H
(1995)
Synthesis and biological activity of 9 substituted acridines

Doi:10.1002/jps.2600620830
(1973)
Metal Complex Lipids for Fluid–Fluid Phase Separation in Coassembled Phospholipid Membranes

Doi:10.1002/anie.202102774
(2021)
Metal-Free and Visible-Light-Promoted C-3 Thiocyanation of 2-Arylquinolin-4-ones

Doi:10.1002/ejoc.201900349
(2019)
Highly stereoselective one-step synthesis of 5-aryl- and 5-(2-styrenyl)-4,5-trans-epoxy-2(E)-pentenols employing an arsonium salt

Doi:10.1016/0040-4039(91)80610-I
(1991)
Doi:10.1016/S0040-4020(01)98784-8
(1970)

Article Doi

Chromium [II]-mediated reductive cleavage of a tertiary halide bearing three β-alkoxy groups. Synthesis of the North hexacyclic steroid unit of the cephalostatin family

DOI: 10.1016/0040-4039(95)00307-X

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0040-4039(95)00307-X

Full text of DOI:10.1016/0040-4039(95)00307-X

Products guided by the article

R&D Labs maybe for 164530-29-4

Relevant to this article

Hot Product