Chromium [II]-mediated reductive cleavage of a tertiary halide bearing three β-alkoxy groups. Synthesis of the North hexacyclic steroid unit of the cephalostatin family

DOI: 10.1016/0040-4039(95)00307-X

Source and publish data:

Tetrahedron Letters p. 2427 - 2430 (1995)

Update date:2022-08-03

Topics:: Authors:

Fuchs

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Article abstract of DOI:10.1016/0040-4039(95)00307-X

Transformation of aldehyde 4 to 17nat, a hexacyclic steroid bearing the requisite functionality and spiroketal stereochemistry of the North portion of the cephalostatin family is described. The key reaction involves CrCl₂ mediated reductive cle

Full text of DOI:10.1016/0040-4039(95)00307-X

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Article Doi

Chromium [II]-mediated reductive cleavage of a tertiary halide bearing three β-alkoxy groups. Synthesis of the North hexacyclic steroid unit of the cephalostatin family

DOI: 10.1016/0040-4039(95)00307-X

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0040-4039(95)00307-X

Full text of DOI:10.1016/0040-4039(95)00307-X

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