16463-37-9Relevant articles and documents
Arylalkene synthesis via decarboxylative cross-coupling of alkenyl halides
Tang, Jie,Goossen, Lukas J.
supporting information, p. 2664 - 2667 (2014/06/09)
A bimetallic catalyst system generated from readily available palladium(II) and copper(I) salts, 1,10-phenanthroline and tri-1-naphthylphosphine was found to efficiently mediate the decarboxylative cross-coupling of alkenyl bromides and chlorides with aromatic carboxylates. It allows the regiospecific synthesis of a broad range of aryl- and heteroarylalkenes in high yields.
Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates
Shang, Rui,Xu, Qing,Jiang, Yuan-Ye,Wang, Yan,Liu, Lei
supporting information; experimental part, p. 1000 - 1003 (2010/06/16)
Chemical Equetion Presentation Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates is achieved by using diglyme as the solvent. The reaction is useful for synthesis of polyfluorobiaryls
Pd-catalyzed decarboxylative Heck vinylation of 2-nitrobenzoates in the presence of CuF2
Goossen, Lukas J.,Zimmermann, Bettina,Knauber, Thomas
supporting information; experimental part, (2010/08/19)
A new protocol for the decarboxylative Heck vinylation of benzoic acids is disclosed. In the presence of a catalyst system generated in situ from Pd(OAc)2 (2 mol %), CuF2 (2 equiv), and benzoquinone (0.5 equiv) in NMP, a wide range of olefins were coupled with various 2-nitrobenzoates at 130 °C with the release of carbon dioxide to afford the corresponding vinyl arenes in good yields.
