16489-73-9Relevant academic research and scientific papers
Direct Evidence for Bromine-Olefin Charge-Transfer Complexes as Essential Intermediates of the Fast Ionic Addition of Bromine to Cyclohexene
Bellucci, Giuseppe,Bianchini, Roberto,Ambrosetti, Roberto
, p. 2464 - 2471 (1985)
The addition of molecular bromine to cyclohexene in 1,2-dichloroethane has been investigated spectrophotometrically with the stopped-flow technique in the 15-35 deg C temperature range with and without cyclohexane added to the reaction medium.The third-or
Transition-State Barrier for Electrophilic Reactions. Solvation of Charge-Transfer Ion Pair as the Unifying Factor in Alkene Addition and Aromatic Substitution with Bromine
Fukuzumi, S.,Kochi, J. K.
, p. 7599 - 7609 (2007/10/02)
Alkenes and arenes are known to form 1:1 electron donor-acceptor complexes with molecular bromine.The disappearance of the charge-transfer (CT) absorption bands for these alkene and aromatic complexes coincides with the kinetics of electrophilic addition
Electrophilic Additions to Olefins. A New Approach to Unifying the Mechanisms of Bromination and Oxymercuration
Fukuzumi, S.,Kochi, J. K.
, p. 2783 - 2791 (2007/10/02)
Bromination and oxymercuration of carbon-carbon double bonds represent classical examples of electrophilic addition, but they nonetheless show quite divergent patterns of reactivities for various olefins.However, the olefin reactivities are identical when
