164987-09-1

Basic information

• Product Name: [1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate
• CAS NO: 164987-09-1
• Molecular Weight: 786.307
• Mol File: 164987-09-1.mol

Chemical Properties

• CAS DataBase Reference: [1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: [1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate(164987-09-1)
• EPA Substance Registry System: [1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate(164987-09-1)

Safety Data

• Hazardous Substances Data: 164987-09-1(Hazardous Substances Data)

Upstream product

• 594-09-2 trimethylphosphane 

Relevant articles and documents

Amphiphilie kationischer η2-Phosphinocarbenkomplexe des Wolframs

η2-Phosphinocarbene complexes of tungsten containing a trimethyl-phosphine ligand show an amphiphilic behavior.With the Lewis acid SMe+ an electrophilic attack occurs at the metal-carbon double bond to give 1-tungsta-2-phospha-4-thiabicyclobutane complexes.On the contrary the Lewis base, PMe3, adds at the carbene carbon atom to yield a cationic trimethylphosphoraneylidene complex.However, treatment of dicarbonyl(η5-cyclopentadienyl)2-(diphenylphosphino)methylcarbene>-tungsten-tetraphenylborate with the less nucleophilic triethylamine causes deprotonation at the methyl group providing dicarbonyl(η5-cyclopentadienyl)-η2-diphenylphosphinovinyltungsten.Keywords: Tungsten; Amphiphilic carbene complexes; Phosphino carbene complexes