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16501-24-9

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16501-24-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 16501-24-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,5,0 and 1 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 16501-24:
(7*1)+(6*6)+(5*5)+(4*0)+(3*1)+(2*2)+(1*4)=79
79 % 10 = 9
So 16501-24-9 is a valid CAS Registry Number.

16501-24-9Relevant articles and documents

The photochemistry of sulfur analogues of dialkyldiazomalonates

Snoonian, John R.,Platz, Matthew S.

, p. 9276 - 9280 (2000)

Laser flash photolysis studies (LFP) of O,S-diethylmonothiodiazomalonate (1) and S,S-dietrryldithiodiazomalonate (2) in 1,1,2-trichlorotrifluoroethane (Freon-113) were consistent with the trapping of an intermediate with λmax = 425 nm, attributed, in the LFP of 1, to that of ylide 10, formed from the reaction of singlet O,S-carboethoxythioethoxycarbene (9) with pyridine. The deduced lifetime of both singlet O,S-dicarboethoxycarbene (9) and S,S-dicarbothioethoxycarbene (13) are essentially the same in Freon-113, but compared to dicarbomethoxycarbene 14, the lifetimes of 9 and 13 were found to be about six times shorter. The LFP studies, in addition to calculations at the B3LYP/6-31 G* level of theory, provide an explanation for the effect of sulfur perturbation that shortens the carbene lifetimes, as well as an explanation for the exclusive migration of the SEt group to ultimately form 5 upon light (300 nm) induced nitrogen extrusion and Wolff rearrangement of 1 in EtOH.

L -Proline Derived Bifunctional Organocatalysts: Enantioselective Michael Addition of Dithiomalonates to trans-β-Nitroolefins

Jin, Hui,Kim, Seung Tae,Hwang, Geum-Sook,Ryu, Do Hyun

, p. 3263 - 3274 (2016/05/19)

A series of novel l-proline derived tertiary amine bifunctional organocatalysts 9 are reported, which were applied to the asymmetric Michael addition of dithiomalonates 2 to trans-β-nitroolefins 1. The reaction proceeded in high yields (up to 99%) with high enantioselectivities (up to 97% ee). The synthetic utility of this methodology was demonstrated in the short synthesis of (R)-phenibut in high yield.

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