16503-25-6

Upstream product

• 106-99-0 buta-1,3-diene 
• 689-97-4 3-buten-1-yne 

Downstream Products

• 1121-54-6 1,3-Cyclohexadiene-1-carbaldehyde 
• 166432-52-6 1,3-undecadien-5-yne 
• 6061-06-9 1,1-dichlorobuta-1,3-diene 
• 2984-42-1 1,4-dichloro-1,3-butadiene 
• 41601-58-5 1,3,4-trichlorobutene 
• 41601-59-6 1,1,4-trichloro-2-butene 
• 3588-12-3 (E,E)-1,4-dichloro-1,3-butadiene 
• 19883-27-3 (3E,5Z)-1,3,5-undecatriene 
• 74885-95-3 3,4,4-trichloro-1-butene 
• 55378-38-6 1,3,4-trichloro-1-butene, cis isomer 
• 55378-39-7 1,3,4-trichloro-1-butene, trans isomer 
• 16356-11-9 (3E,5E)-1,3,5-undecatriene 
• 478176-01-1 (E)-N-(but-2-yn-1-yl)-4-methyl-N-(penta-2,4-dien-1-yl)benzenesulfonamide 

Relevant academic research and scientific papers

Gas phase surface-catalyzed HCl addition to vinylacetylene: motion along a catalytic surface. Experiment and theory

Gaseous mixtures of HCl and vinylacetylene were permitted to react in Pyrex IR cells (NaCl windows). Gaseous 4-chloro-1,2-butadiene and 2-chloro-1,3-butadiene (chloroprene) were the major products. Kinetic data (FTIR) generated a rate expression in concert with surface catalysis. Computational studies involving surface associated water provide a view that accounts for the experimentally determined orders and a bifurcated pathway producing both products. The results are in accord with wall-adsorbed reactant(s) as well as previously reported computational studies on the reactants.