16503-80-3Relevant academic research and scientific papers
Tricomponent catalytic α,α-difluorination of acid chlorides
Bloom, Steven,Scerba, Michael T.,Erb, Jeremy,Lectka, Thomas
supporting information; experimental part, p. 5068 - 5071 (2011/11/29)
The selective α,α-difluorination of carbonyl compounds remains a challenge in modern organic synthesis; current methods often incorporate stepwise processes and/or harsh conditions, providing unsatisfactory mixtures of mono- and difluorinated products. In this communication, a practical, mild, and one-pot method for the selective α,α-difluorination of readily available acid chlorides is reported in which three separate catalysts act synergistically to form products in outstanding selectivity and fair to excellent yields.
Adsorption effects on the selective electrofluorination of α-(phenylthio)acetamides and α-(phenylthio)acetates in Et3N·3HF/CH3CN
Suryanarayanan,Chellammal,Noel
, p. 53 - 59 (2007/10/03)
Cyclic voltammetric behaviour of α-(phenylthio)acetamides and α-(phenylthio)acetates were compared in CH3CN/tetrabutylammonium perchlorate (TBAP) and CH3CN/Et3N·3HF to assess the influence of fluoride ion on the oxidative
