165066-23-9Relevant academic research and scientific papers
Synthesis and structure of tricyclic furanosesquiterpenoids related to pallescensin A
Moiseenkov, A. M.,Lozanova, A. V.,Surkova, A. A.,Dragan, V. A.,Strelenko, Yu. A.,Buevich, A. V.
, p. 153 - 160 (1994)
Electrophilic cyclization of (cyclo)farnesanes containing an exo-methylene group in the α-isoprenoid unit smoothly gives regio- and stereoisomeric octalins subsequently trans formed to tricyclic furanosesquiterpenoids related to metabolites of some marine organisms. - Key words: furanosesquiterpenoids, pallescensin A, (cyclo)farnesanes, electrophilic cyclization; 1H and 13C NMR spectra, Z-HMQC; molecular mechanics, conformational analysis.
