Russian Chemical Bulletin p. 153 - 160 (1994)
Update date:2022-08-03
Topics:
Moiseenkov, A. M.
Lozanova, A. V.
Surkova, A. A.
Dragan, V. A.
Strelenko, Yu. A.
Buevich, A. V.
Electrophilic cyclization of (cyclo)farnesanes containing an exo-methylene group in the α-isoprenoid unit smoothly gives regio- and stereoisomeric octalins subsequently trans formed to tricyclic furanosesquiterpenoids related to metabolites of some marine organisms. - Key words: furanosesquiterpenoids, pallescensin A, (cyclo)farnesanes, electrophilic cyclization; 1H and 13C NMR spectra, Z-HMQC; molecular mechanics, conformational analysis.
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