Synthesis and structure of tricyclic furanosesquiterpenoids related to pallescensin A

DOI: 10.1007/BF00699157

Source and publish data:

Russian Chemical Bulletin p. 153 - 160 (1994)

Update date:2022-08-03

Topics:

Authors:

Moiseenkov, A. M.

Lozanova, A. V.

Surkova, A. A.

Dragan, V. A.

Strelenko, Yu. A.

Buevich, A. V.

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Article abstract of DOI:10.1007/BF00699157

Electrophilic cyclization of (cyclo)farnesanes containing an exo-methylene group in the α-isoprenoid unit smoothly gives regio- and stereoisomeric octalins subsequently trans formed to tricyclic furanosesquiterpenoids related to metabolites of some marine organisms. - Key words: furanosesquiterpenoids, pallescensin A, (cyclo)farnesanes, electrophilic cyclization; 1H and 13C NMR spectra, Z-HMQC; molecular mechanics, conformational analysis.

Full text of DOI:10.1007/BF00699157

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