16510-36-4

Basic information

• Product Name: DL-2,3-Dimethyl-2,3-diphenylbernsteinsaeuredinitril
• CAS NO: 16510-36-4
• Molecular Weight: 260.338
• Mol File: 16510-36-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: DL-2,3-Dimethyl-2,3-diphenylbernsteinsaeuredinitril(CAS DataBase Reference)
• NIST Chemistry Reference: DL-2,3-Dimethyl-2,3-diphenylbernsteinsaeuredinitril(16510-36-4)
• EPA Substance Registry System: DL-2,3-Dimethyl-2,3-diphenylbernsteinsaeuredinitril(16510-36-4)

Safety Data

• Hazardous Substances Data: 16510-36-4(Hazardous Substances Data)

Upstream product

• 1200-71-1 2-cyano-2-phenylpropionic acid 
• 1823-91-2 1-phenylethyl cyanide 
• 82026-89-9 2-bromo-2-phenylpropionitrile 
• 15681-48-8 lithium dimethylcuprate 
• 29738-05-4 2-cyano-2-phenyl-propionyl chloride 
• 140-29-4 phenylacetonitrile 
• 110-89-4 piperidine 

Downstream Products

• 1823-91-2 1-phenylethyl cyanide 

Relevant articles and documents

The synthesis and stereospecific solid-state photodecarbonylation of hexasubstituted meso- and d,l-ketones

Tertiary carbanions were trapped with half an equivalent of diphosgene to give meso- and d,l-hexasubstituted ketones in moderate yields and modest diastereoselectivities. The ketones were also synthesized by a step-wise synthesis in which the carbonyl group was first installed as an acid before activation and the second nucleophilic attack. This second method gave lower yields but similar diastereoselectivites. Steric limits of both methods were also determined. The photolysis of the resulting crystalline ketones gave a mixture of products in solution, but took place chemoselectively and diastereospecifically in the solid-state. The Royal Society of Chemistry and Owner Societies.