16522-66-0Relevant articles and documents
Reaction of organylchlorosilanes with dimethyl sulfoxide in the presence of octamethyltrisiloxane
Basenko,Gebel',Boyarkina,Voronkov
, p. 882 - 884 (2004)
Dichloro(methyl)(vinyl)silane reacts with DMSO in the presence of octamethyltrisiloxane to form cyclooligomethyl(vinyl)siloxanes(MeViSiO) n (n = 3-6). The reaction involves disproportionation of octamethyltrisiloxane into hexamethyldisiloxane and decamethyltetrasiloxane. Along with the latter two products, insertion products of methyl vinyl silanone into both permethyloligosiloxanes were identified. Alkyltrichlorosilanes RSiCl3 (R = Me, Et) react with DMSO in the presence of octamethyltrisiloxane to form cyclic oligoalkyltrichlorosiloxanes (RClSiO) m (m = 3-6).