16529-03-6Relevant articles and documents
Rhodium nanoparticles supported on carbon nanofibers as an arene hydrogenation catalyst highly tolerant to a coexisting epoxido group
Motoyama, Yukihiro,Takasaki, Mikihiro,Yoon, Seong-Ho,Mochida, Isao,Nagashima, Hideo
supporting information; experimental part, p. 5042 - 5045 (2009/12/28)
Rhodium nanoparticles supported on a carbon nanofiber (Rh/CNF-T) show high catalytic activity toward arene hydrogenation under mild conditions in high turnover numbers without leaching the Rh species; the reaction is highly tolerant to epoxido groups, which often undergo ring-opening hydrogenation with conventional catalysts.
A simple and efficient method for epoxidation of terminal alkenes
Coperet, Christophe,Adolfsson, Hans,Sharpless, K. Barry
, p. 1565 - 1566 (2007/10/03)
The use of a catalytic amount of 3-cyanopyridine in the methyltrioxorhenium catalysed epoxidation of terminal alkenes with aqueous hydrogen peroxide speeds turnover, which results in the formation of many functionalized epoxides in high yields.
DEPLACEMENTS HOMOLYTIQUES INTRAMOLECULAIRES: 15 - ADDITIONS RADICALAIRES A DES PEROXYDES β-ETHYLENIQUES
Montaudon, E .,Agorrody, M.,Rakotomanana, F.,Maillard, B.
, p. 769 - 774 (2007/10/02)
Free radical additions of cyclohexane, tetrahydrofuran, methyl propanoate, acetonitrile, dichloromethane to allyl t-butyl peroxide, t-butyl 2-methyl prop-2-enyl peroxide, t-butyl 2,2-dimethyl prop-2-enyl peroxide and t-butyl 3-methyl but-2-enyl peroxide h
