165403-98-5Relevant academic research and scientific papers
A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for its Rearrangement
Ohlmann, Dietmar,Pritzkow, Hans,Gruetzmacher, Hansjoerg,Anthamatten, Mitchell,Glaser, Rainer
, p. 1011 - 1012 (1995)
Copper(I) oxide reacts with selenol 2,4,6-Pri3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate i3C6H2)>>6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.
