A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for its Rearrangement

DOI: 10.1039/c39950001011

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1011 - 1012 (1995)

Update date:2022-08-05

Topics:

Authors:

Ohlmann, Dietmar

Pritzkow, Hans

Gruetzmacher, Hansjoerg

Anthamatten, Mitchell

Glaser, Rainer

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001011

Copper(I) oxide reacts with selenol 2,4,6-Prⁱ3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate i3C6H2)>>6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

Full text of DOI:10.1039/c39950001011

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[[(CH₃)2CH]3C₆H₂Se]6Cu₆

Cas No:165403-98-5

R&D Labs maybe for 165403-98-5

Changzhou Sunsheng Chem Co., Ltd

Contact:+1-(989)-854-0648

Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Nanjing HuiBaiShi Biotechnology Co.,Ltd.

Contact:+86 (25)58745219

Address:No.606 Ningliu Road,LiuHe District.
Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China

Relevant to this article

CYCLOADDITION OF ANHYDRO BASES OF HETEROCYCLIC CATIONS. 2. SYNTHESIS OF SPIROCYCLIC AND CARCASS STRUCTURES IN THE REACTION OF s-TETRAZINES WITH THE ANHYDRO BASE OF QUATERNARY LEPIDINIUM SALT

Doi:10.1007/BF00471755
(1991)
Asymmetric Synthesis of 3-Substituted 2-exo-Methylenealkanones by Addition-Elimination Reaction Using a Chiral Leaving Group and Organometallic Nucleophiles

Doi:10.1021/jo00044a026
(1992)
Dendron to central core S₁-S₁ and S ₂-S_n (n>1) energy transfers in artificial special pairs containing dendrimers with limited numbers of conformations

Doi:10.1002/chem.201203033
(2013)
Rapid access to unsymmetrical 1,3-diynes and 2,5-disubstituted thiophenes under ligand and Pd/Ni-free Cu-catalysis

Doi:10.1039/c5ra15705f
(2015)
Doi:10.1021/jo01033a002
(1964)
Studies on the regioselective nucleophilic aromatic substitution (S _NAr) reaction of 2-substituted 3,5-dichloropyrazines

Doi:10.1021/ol4006695
(2013)

Article Doi