Journal of the Chemical Society. Chemical communications p. 1011 - 1012 (1995)
Update date:2022-08-05
Topics:
Ohlmann, Dietmar
Pritzkow, Hans
Gruetzmacher, Hansjoerg
Anthamatten, Mitchell
Glaser, Rainer
Copper(I) oxide reacts with selenol 2,4,6-Pri3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.
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