A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for its Rearrangement

DOI: 10.1039/c39950001011

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1011 - 1012 (1995)

Update date:2022-08-05

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Authors:

Ohlmann, Dietmar

Pritzkow, Hans

Gruetzmacher, Hansjoerg

Anthamatten, Mitchell

Glaser, Rainer

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Article abstract of DOI:10.1039/c39950001011

Copper(I) oxide reacts with selenol 2,4,6-Prⁱ3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate i3C6H2)>>6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

Full text of DOI:10.1039/c39950001011

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