A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for its Rearrangement

DOI: 10.1039/c39950001011

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1011 - 1012 (1995)

Update date:2022-08-05

Topics:

Authors:

Ohlmann, Dietmar

Pritzkow, Hans

Gruetzmacher, Hansjoerg

Anthamatten, Mitchell

Glaser, Rainer

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001011

Copper(I) oxide reacts with selenol 2,4,6-Prⁱ3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate i3C6H2)>>6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

Full text of DOI:10.1039/c39950001011

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[[(CH₃)2CH]3C₆H₂Se]6Cu₆

Cas No:165403-98-5

R&D Labs maybe for 165403-98-5

Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china

Relevant to this article

CYCLOADDITION OF ANHYDRO BASES OF HETEROCYCLIC CATIONS. 2. SYNTHESIS OF SPIROCYCLIC AND CARCASS STRUCTURES IN THE REACTION OF s-TETRAZINES WITH THE ANHYDRO BASE OF QUATERNARY LEPIDINIUM SALT

Doi:10.1007/BF00471755
(1991)
Asymmetric Synthesis of 3-Substituted 2-exo-Methylenealkanones by Addition-Elimination Reaction Using a Chiral Leaving Group and Organometallic Nucleophiles

Doi:10.1021/jo00044a026
(1992)
Dendron to central core S₁-S₁ and S ₂-S_n (n>1) energy transfers in artificial special pairs containing dendrimers with limited numbers of conformations

Doi:10.1002/chem.201203033
(2013)
Rapid access to unsymmetrical 1,3-diynes and 2,5-disubstituted thiophenes under ligand and Pd/Ni-free Cu-catalysis

Doi:10.1039/c5ra15705f
(2015)
Doi:10.1021/jo01033a002
(1964)
Studies on the regioselective nucleophilic aromatic substitution (S _NAr) reaction of 2-substituted 3,5-dichloropyrazines

Doi:10.1021/ol4006695
(2013)

Article Doi