165600-76-0Relevant academic research and scientific papers
Ligand Substitution in and the Isomerism of
Lin, Jiann T.,Chou, Yung Chun,Shih, Yeh E.,Hong, Fong E.,Wen, Yuh S.,et al.
, p. 1791 - 1798 (2007/10/02)
Treatment of with NO(1+)BF4(1-) provided 1.Several phosphide-bridged diiron complexes, (R = Me 2, OMe 3 or Ph 4), 5-C5H4PPh2)2Fe 14> and 3(NO)(μ-PPh2)> 15, have been derived from ligand substitution in 1.These complexes exhibit structural versatility.Interconversion between two isomers of 5, 5b and 5c, has been established by variable-temperature 31P- NMR, two-dimensional exchange spectroscopy and single-crystal structure determination.
