165617-57-2Relevant academic research and scientific papers
Effects of chalcogen atom variation in chalcogenadiazole fused indolo[2,3-: A] carbazoles
Ghosh, Sirina,Kumar, Neha Rani,Zade, Sanjio S.
, p. 6889 - 6895 (2018)
A series of chalcogenadiazole fused indolo[2,3-a]carbazoles 1-3 were prepared, wherein a chalcogen atom was varied from oxygen (O) to sulphur (S) to selenium (Se) in the chalcogenadiazole unit. A Cadogan ring closing reaction was used as the key synthetic step for the preparation of 1-3. The chalcogen alteration (O, S and Se) led to a significant change in the structural, optical and electrochemical properties of 1-3, indicating a subsequent change in their HOMO-LUMO energy levels. Density functional theory (DFT) calculations were performed to further support the experimentally observed trend.
HETEROCYCLIC COMPOUND, AND ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC ELECTROLUMINESCENCE DISPLAY DEVICE INCLUDING THE SAME
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, (2019/04/05)
Provided are a heterocyclic compound represented by Formula 1 and an organic electroluminescence device and an organic electroluminescence display device including the heterocyclic compound represented by Formula 1 in an emission layer. In Formula 1, A is represented by Formula 2, D1 is represented by Formula 3, and D2 is represented by Formula 4.
THIADIAZOLE COMPOUND, COMPOUND FOR LIGHT EMITTING ELEMENT, LIGHT EMITTING ELEMENT, LIGHT EMITTING DEVICE, AUTHENTICATION DEVICE AND ELECTRONIC APPARATUS
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, (2016/10/08)
PROBLEM TO BE SOLVED: To provide an efficient and long-life thiadiazole compound which emits light in the near-infrared region, and a light emitting element or the like prepared using the same. SOLUTION: A light emitting element 1 comprises an anode 3, a cathode 9, and a light emission layer 6 provided between the anode 3 and the cathode 9, wherein the light emission layer 6 comprises a thiadiazole compound represented by formula (1) and a compound of formula IRH-1. In the formula (1), A is H, an alkyl group or the like, and in the formula IRH-1, n is a natural number of 1-12 and R is H, alkyl or the like. COPYRIGHT: (C)2016,JPOandINPIT
Electronic device
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, (2016/10/09)
PROBLEM TO BE SOLVED: To provide a thiadiazole compound, a compound for light-emitting elements, and a light-emitting element capable of emitting light in the near-infrared region and having high efficiency and long life, and a light-emitting device, an authentication device, and an electronic device having the light-emitting element. SOLUTION: A light-emitting element 1 comprises an anode 3, a cathode 9, and a light-emitting layer 6 provided between the anode 3 and the cathode 9. The light-emitting layer 6 is configured to contain a compound represented by formula (1) and a compound represented by formula IRH-1. In the formula (1), A and B each represent an aryl group, an arylamino group or triarylamine. In the formula IRH-1, n represents a natural number of 1 to 12; and each R is a substituent or a functional group, and represents an aryl group or an arylamino group which may have H, an alkyl group or a substituent. COPYRIGHT: (C)2015,JPOandINPIT
π-Extended thiadiazoles fused with thienopyrrole or indole moieties: Synthesis, structures, and properties
Kato, Shin-Ichiro,Furuya, Takayuki,Kobayashi, Atsushi,Nitani, Masashi,Ie, Yutaka,Aso, Yoshio,Yoshihara, Toshitada,Tobita, Seiji,Nakamura, Yosuke
, p. 7595 - 7606 (2012/11/13)
We report the syntheses, structures, photophysical properties, and redox characteristics of donor-acceptor-fused π-systems, namely π-extended thiadiazoles 1-5 fused with thienopyrrole or indole moieties. They were synthesized by the Stille coupling reacti
THIADIAZOLE-BASED COMPOUND, LIGHT EMITTING ELEMENT COMPOUND, LIGHT EMITTING ELEMENT, LIGHT EMITTING DEVICE, AUTHENTICATION DEVICE, AND ELECTRONIC DEVICE
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Page/Page column 43, (2012/11/07)
Provided is a thiadiazole compound with high efficiency and long life which emits light in a near-infrared region and represented by Formula (I). [In the Formula (I), As each independently represent an aryl group which may have a substituent or a diarylamino group.]
Synthesis and properties of benzobis(thiadiazole)s with nonclassical π-electron ring systems
Yamashita, Yoshiro,Ono, Katsuhiko,Tomura, Masaaki,Tanaka, Shoji
, p. 10169 - 10178 (2007/10/03)
Benzo[1,2-c:4,5-c']bis([1,2,5]thiadiazole) containing a hypervalent sulfur atom has a low LUMO energy. The aryl derivatives were synthesized using a Stille coupling reaction. The selenadiazole analogues were also prepared. The electron accepting properties of these nonclassical heterocycles were shown by their high reduction potentials. Introduction of electron-donating groups into the electron-withdrawing heterocycles afforded novel donor-acceptor compounds. Their cyclic vollammograms showed that they are easily both oxidized and reduced. Some of them have the absorption maxima above 700 nm due to the small HOMO-LUMO separation. X-ray structure analysis of the diphenyl derivative revealed the formation of a tape-like network through short S···N contacts.
