16576-77-5Relevant academic research and scientific papers
Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
Delmas, Luke C.,Horton, Peter N.,White, Andrew J. P.,Coles, Simon J.,Lickiss, Paul D.,Davies, Robert P.
, p. 12524 - 12527 (2017)
A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(ii) gave IMP-18-a 3D MOF incorporating Si-O-Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(ii).
